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Title: | Secondary metabolites from endemic species Iris adriatica Trinajstić ex Mitić (Iridaceae) | Authors: | Bukvički, Danka Novaković, Miroslav Ab Ghani, Nurunajah Marin, Petar Asakawa, Yoshinori |
Keywords: | 1D and 2D NMR;HR-EI-MS;Iris adriatica;isoflavonoids;rhizome | Issue Date: | 3-Aug-2018 | Rank: | M22 | Journal: | Natural Product Research | Abstract: | © 2017, © 2017 Informa UK Limited, trading as Taylor & Francis Group. This manuscript describes the first detailed chemical investigation of endemic species Iris adriatica, including isolation and structure elucidation. Chemical analyses of the rhizome CH2Cl2/MeOH (2:1) extract revealed fourteen secondary metabolites, mainly isoflavonoids. Among isoflavonoids, two groups have been found: nigricin-type and tectorigenin-type. Dominant group of the isolated compounds has been nigricin-type isoflavones: nigricin, nigricin-4′-(1-O-β-D-glucopyranoside) and nigricin-4′-(1-O-β-D-glucopyranosyl (1–6)-β-D-glucopyranoside) with 2.5, 10 and 1% of the total extract, respectively. Irisxanthone–xanthone C-glucoside, β-sitosterol, benzophenone and one of its derivatives have also been found. Nigricin-type isoflavonoids and irisxanthone can be considered as possible chemotaxonomic markers for I. adriatica. 5,3′,5′-Trimethoxy-6,7-methylenedioxyisoflavone-4′-(1-O-β-D-glucopyranoside) and benzophenone have been isolated from Iris species for the first time. |
URI: | https://biore.bio.bg.ac.rs/handle/123456789/2714 | ISSN: | 1478-6419 | DOI: | 10.1080/14786419.2017.1402309 |
Appears in Collections: | Journal Article |
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