Please use this identifier to cite or link to this item: https://biore.bio.bg.ac.rs/handle/123456789/820
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dc.contributor.authorPagnacco, Maja C.en_US
dc.contributor.authorMaksimović, Jelena P.en_US
dc.contributor.authorPotkonjak, Nebojša I.en_US
dc.contributor.authorBožić, Bojanen_US
dc.contributor.authorHorváth, Attila K.en_US
dc.date.accessioned2019-07-12T20:32:34Z-
dc.date.available2019-07-12T20:32:34Z-
dc.date.issued2018-01-18-
dc.identifier.issn1089-5639-
dc.identifier.urihttps://biore.bio.bg.ac.rs/handle/123456789/820-
dc.description.abstractThe Briggs-Rauscher reaction containing malonic acid may undergo a sudden transition from low (state I) to high iodide and iodine (state II) concentration states after a well-defined and strongly reproducible oscillatory period. This study clearly shows that even though the time-dependent behavior of the oscillatory state is reproducible, the time lag necessary for the appearance of the state I to state II transition after the system leaves the oscillatory state becomes irreproducible for an individual kinetic run. This crazy clock behavior of the state I to state II transition is identified by repeated experiments in which stirring rate is taken as a control parameter and all other parameters such as initial conditions, temperature, vessel surface, and the age of solution were kept constant. Surprisingly, a better stirring condition does not make the transition reproducible; it simply does not allow the transition to happen at all. The proposed mechanism, additional explanations, and proposals for this irreproducibility of state I to state II transition have been presented. Considering the fact that the number of crazy clock reactions is only a few, this study may contribute to a better understanding of fundaments of this phenomenon.en_US
dc.language.isoenen_US
dc.relation.ispartofJournal of Physical Chemistry Aen_US
dc.titleTransition from Low to High Iodide and Iodine Concentration States in the Briggs-Rauscher Reaction: Evidence on Crazy Clock Behavioren_US
dc.typeArticleen_US
dc.identifier.doi10.1021/acs.jpca.7b11774-
dc.identifier.pmid29254335-
dc.identifier.scopus2-s2.0-85040764226-
dc.identifier.urlhttps://api.elsevier.com/content/abstract/scopus_id/85040764226-
dc.description.rankM22en_US
dc.description.startpage482en_US
dc.description.endpage491en_US
dc.description.volume122en_US
dc.description.issue2en_US
item.fulltextWith Fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
item.grantfulltextrestricted-
item.openairetypeArticle-
item.languageiso639-1en-
crisitem.author.deptChair of General Physiology and Biophysics-
crisitem.author.orcid0000-0001-9910-2741-
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