Please use this identifier to cite or link to this item:
https://biore.bio.bg.ac.rs/handle/123456789/5970
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Vujisić, Ljubodrag | en_US |
dc.contributor.author | Vučković, Ivan | en_US |
dc.contributor.author | Makarov, Slobodan | en_US |
dc.contributor.author | Ilić, Bojan | en_US |
dc.contributor.author | Antić, Dragan | en_US |
dc.contributor.author | Jadranin, Milka | en_US |
dc.contributor.author | Todorović, Nina | en_US |
dc.contributor.author | Mrkić, Ivan | en_US |
dc.contributor.author | Vajs, Vlatka | en_US |
dc.contributor.author | Lučić, Luka | en_US |
dc.contributor.author | Ćurčić, Božidar | en_US |
dc.contributor.author | Mitić, Bojan. | en_US |
dc.date.accessioned | 2023-04-13T08:53:57Z | - |
dc.date.available | 2023-04-13T08:53:57Z | - |
dc.date.issued | 2013 | - |
dc.identifier.uri | https://biore.bio.bg.ac.rs/handle/123456789/5970 | - |
dc.description.abstract | The geophilomorph centipede, Himantarium gabrielis, when disturbed, discharges a viscous and proteinaceous secretion from the sternal glands. This exudate was found by gas chromatography-mass spectrometry, liquid chromatography-high resolution mass spectrometry, liquid chromatography-mass spectrometry-mass spectrometry and NMR analyses to be composed of hydrogen cyanide, benzaldehyde, benzoyl nitrile, benzyl nitrile, mandelonitrile, mandelonitrile benzoate, 3,7,6O-trimethylguanine (himantarine), farnesyl 2,3-dihydrofarnesoate and farnesyl farnesoate. This is the first report on the presence of benzyl nitrile and mandelonitrile benzoate in secreted substances from centipedes. Farnesyl 2,3-dihydrofarnesoate is a new compound, while himantarine and farnesyl farnesoate were not known as natural products. A post-secretion release of hydrogen cyanide by reaction of mandelonitrile and benzoyl nitrile was observed by NMR, and hydrogen cyanide signals were completely assigned. In addition, a protein component of the secretion was analysed by electrophoresis which revealed the presence of a major 55 kDa protein. Analyses of the defensive exudates of other geophilomorph families should produce further chemical surprises. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Springer, New York | en_US |
dc.relation.ispartof | Science of Nature - Naturwissenschaften | en_US |
dc.subject | Chemical deterrents; | en_US |
dc.subject | Geophilomorphs; | en_US |
dc.subject | Viscid proteinaceous secretion; | en_US |
dc.subject | Himantarine; | en_US |
dc.subject | Farnesyl 2,3-dihydrofarnesoate; | en_US |
dc.subject | Montenegro. | en_US |
dc.title | Chemistry of the sternal gland secretion of the Mediterranean centipede Himantarium gabrielis (Linnaeus, 1767) (Chilopoda: Geophilomorpha: Himantariidae) | en_US |
dc.type | Journal Article | en_US |
dc.identifier.doi | 10.1007/s00114-013-1086-6 | - |
dc.description.rank | M21 | en_US |
dc.description.impact | 2.278 | en_US |
dc.description.startpage | 861 | en_US |
dc.description.endpage | 870 | en_US |
dc.relation.issn | 0028-1042 | en_US |
dc.description.volume | 100 | en_US |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
item.openairetype | Journal Article | - |
item.languageiso639-1 | en | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
crisitem.author.dept | Chair of Animal Development | - |
crisitem.author.dept | Chair of Animal Development | - |
crisitem.author.dept | Chair of Animal Development | - |
crisitem.author.dept | Chair of Animal Development | - |
crisitem.author.dept | Chair of Animal Development | - |
crisitem.author.orcid | 0000-0002-4365-8182 | - |
crisitem.author.orcid | 0000-0001-9051-0415 | - |
crisitem.author.orcid | 0000-0002-1231-4213 | - |
crisitem.author.orcid | 0000-0001-8397-7279 | - |
crisitem.author.orcid | 0000-0003-4507-7629 | - |
Appears in Collections: | Journal Article |
SCOPUSTM
Citations
9
checked on May 14, 2024
Page view(s)
20
checked on May 15, 2024
Google ScholarTM
Check
Altmetric
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.